Functionalization of molecular architectures : advances and applications on low-dimensional compounds /
edited by Kazuhiro Shikinaka.
- 1 online resource (viii, 164 pages)
Low-Dimensional Compounds for Diverse Material Sciences / Kazuhiro Shikinaka -- Stimuli-Responsive Materials Consisting of Rigid Cylindrical Inorganic Low-Dimensional Compound "Imogolite" / Kazuhiro Shikinaka -- Preparation, Modification, and Hybridization of One-Dimensional Ionic Ladder-Like Polysilsesquioxanes / Yoshiro Kaneko -- Dimensionality Transformation of Layered Materials toward the Design of Functional Nanomaterials / Yoshiyuki Kuroda -- Inorganic Nanosheets as Soft Materials / Nobuyoshi Miyamoto, Shinya Anraku, and Morio Shintate.
Low-dimensional compounds are molecules that correspond to various shapes, such as rod, ladder (one-dimensional compounds), and sheet (two-dimensional compounds). They are ordinarily found in electromagnetic fields. Recently, versatile low-dimensional compounds were proposed for use as components of various functional materials. These new-class low-dimensional compounds contribute significantly to industrial/materials sciences. The molecular architecture consisting of low-dimensional compounds can also be found in nature. One example is the cell cytoskeleton, which is a network- or bundle-like architecture consisting of rod-like protein assemblies. The cell accomplishes its motility by structural transition of the cytoskeleton--that is, phase transition of the architecture of low-dimensional compounds in response to some stimuli induces shape changes in cells. Another example is nacre, which is composed of layered aragonite platelets, usually a metastable CaCO3 polymorph. The layered inorganic platelets give nacre its stiffness and noncombustibility. Thus, the molecular architecture of low-dimensional compounds in natural life contributes to their functionality. This book reviews various advanced studies on the application of low-dimensional compounds and is, therefore, important for the development of materials sciences and industrial technologies.