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Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion [electronic resource] / by Zhandong Wang.

By: Wang, Zhandong [author.].
Contributor(s): SpringerLink (Online service).
Material type: materialTypeLabelBookSeries: Springer Theses, Recognizing Outstanding Ph.D. Research: Publisher: Singapore : Springer Nature Singapore : Imprint: Springer, 2018Edition: 1st ed. 2018.Description: XIII, 216 p. 119 illus., 42 illus. in color. online resource.Content type: text Media type: computer Carrier type: online resourceISBN: 9789811056932.Subject(s): Thermodynamics | Heat engineering | Heat transfer | Mass transfer | Pollution | Physical chemistry | Engineering Thermodynamics, Heat and Mass Transfer | Pollution | Thermodynamics | Physical ChemistryAdditional physical formats: Printed edition:: No title; Printed edition:: No title; Printed edition:: No titleDDC classification: 621.4021 Online resources: Click here to access online
Contents:
Introduction -- Experimental method and kinetic modeling -- Experimental and modeling study of cyclohexane combustion -- Experimental and modeling study of methylcyclohexane combustion -- Experimental and modeling study of ethylcyclohexane combustion -- Combustion kinetics of cyclohexane and C1-C2 mono-alkyl cyclohexanes -- Conclusions and perspective.
In: Springer Nature eBookSummary: This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.
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Introduction -- Experimental method and kinetic modeling -- Experimental and modeling study of cyclohexane combustion -- Experimental and modeling study of methylcyclohexane combustion -- Experimental and modeling study of ethylcyclohexane combustion -- Combustion kinetics of cyclohexane and C1-C2 mono-alkyl cyclohexanes -- Conclusions and perspective.

This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

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