000 05097cam a2200637 i 4500
001 on1089881503
003 OCoLC
005 20220711203508.0
006 m o d
007 cr cnu---unuuu
008 190308t20192019nju ob 001 0 eng
010 _a 2019011509
040 _aDLC
_beng
_erda
_epn
_cDLC
_dOCLCO
_dN$T
_dEBLCP
_dDG1
_dRECBK
_dOCLCF
_dYDX
_dOCLCQ
_dYUS
_dUKAHL
019 _a1100890952
020 _a9781119460398
_q(electronic book)
020 _a1119460395
_q(electronic book)
020 _a9781119460374
_q(electronic book)
020 _a1119460379
_q(electronic book)
020 _a9781119460237
_q(electronic book)
020 _a1119460239
_q(electronic book)
020 _z9781119460244
_q(hardcover)
024 8 _a16179963
029 1 _aAU@
_b000065219438
029 1 _aCHNEW
_b001050877
029 1 _aCHVBK
_b567422305
035 _a(OCoLC)1089881503
_z(OCoLC)1100890952
042 _apcc
050 1 4 _aQD411
_b.H37 2019
072 7 _aSCI
_x013040
_2bisacsh
082 0 0 _a547/.05
_223
049 _aMAIN
100 1 _aHashemi, Lida,
_eauthor.
_98218
245 1 0 _aPillared metal-organic frameworks properties and applications /
_cLida Hashemi and Ali Morsali.
264 1 _aHoboken, New Jersey :
_bJohn Wiley & Sons, Inc. ;
_aBeverly, MA :
_bScrivener Publishing, LLC,
_c2019.
264 4 _c©2019
300 _a1 online resource
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
504 _aIncludes bibliographical references and index.
505 0 _aIntro; Title page; Copyright page; Preface; Abbreviations; Chapter 1: Introduction to Metal-Organic Frameworks; 1.1 What are the Metal-Organic Frameworks?; 1.2 Synthesis of Metal-Organic Frameworks; 1.3 Structural Highlights of Metal-Organic Frameworks; 1.4 Expansion of Metal-Organic Frameworks Structures; 1.5 High Thermal and Chemical Stability; 1.6 Applications of Metal-Organic Frameworks; 1.7 Conclusion; References; Chapter 2: Pillar-Layer Metal-Organic Frameworks; 2.1 Introduction; 2.2 Topology and Diversity in Pillar-Layered MOFs; 2.3 Synthesis Methods in Pillar-Layered MOFs
505 8 _a2.4 Linkers in Pillar-Layered MOFs2.5 Conclusion; References; Chapter 3: Rigid and Flexible Pillars; 3.1 Introduction; 3.2 Conclusion; References; Chapter 4: Introduction to N-donor Pillars; 4.1 Introduction; 4.2 Bipyridine; 4.3 Dabco; 4.4 Imidazole and Pyrazole; 4.5 Triazole and Tetrazole; 4.6 Pyrazine and Pipyrazine; 4.7 Amide, Imide, Amin and Azine/Azo Spacer; 4.8 Conclusion; References; Chapter 5: Introduction to Aromatic and Aliphatic Pillars; 5.1 Introduction; 5.2 Non-Interpentrated Frameworks; 5.3 Frameworks with Interpenetration; 5.4 Control over Interpenetration; 5.5 Conclusion
520 _aIn the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF's pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.
588 0 _aOnline resource; title from digital title page (viewed on June 10, 2019).
650 0 _aOrganometallic chemistry.
_98219
650 0 _aPorous materials.
_97874
650 7 _aSCIENCE
_xChemistry
_xOrganic.
_2bisacsh
_95920
650 7 _aOrganometallic chemistry.
_2fast
_0(OCoLC)fst01047969
_98219
650 7 _aPorous materials.
_2fast
_0(OCoLC)fst01071907
_97874
655 4 _aElectronic books.
_93294
700 1 _aMorsali, Ali,
_eauthor.
_98220
776 0 8 _iPrint version:
_aHashemi, Lida.
_tPillared metal-organic frameworks properties and applications.
_dHoboken, New Jersey : John Wiley & Sons, Inc. ; Salem, Massachusetts : Scrivener Publishing, LLC, [2019]
_z9781119460244
_w(DLC) 2019009263
856 4 0 _uhttps://doi.org/10.1002/9781119460237
_zWiley Online Library
942 _cEBK
994 _a92
_bDG1
999 _c69043
_d69043